Photoelectrocatalytic performances of nanostructured/decorated TiO 2 electrodes: Effect of wavelength and cell configuration

The behaviour of TiO2 based electrodes was investigated during the photoelectrocatalytic water splitting process. TiO2 nanotubes and compact oxide structures were obtained by electrochemical oxidation of Ti foils. A subsequent hydrothermal process carried out at both the nanotubular and compact oxide structures allowed decorating the structure by TiO2 nanoparticles. The synthesized TiO2 samples worked as photoanodes both in a bulk three electrode cell and in a thin gap cell. The results from measurements of the photocurrent and from electrochemical impedance spectroscopy were used to highlight a combined effect of the wavelength of the incident light and the kind of cell configuration, on the global performance of the systems. The results indicate that the decoration process does not result only in a simple increase of the specific surface, but it also determines a different concentration of the bulk and superficial sites in the electrode. The different response of the sites at different wavelengths, along with the accessibility of the electrolyte to the porous structure are evocated to justify the experimental behaviour observed

The Virtual Element Method with curved edges

In this paper we initiate the investigation of Virtual Elements with curved faces. We consider the case of a fixed curved boundary in two dimensions, as it happens in the approximation of problems posed on a curved domain or with a curved interface. While an approximation of the domain with polygons leads, for degree of accuracy $k \geq 2$, to a sub-optimal rate of convergence, we show (both theoretically and numerically) that the proposed curved VEM lead to an optimal rate of convergence

Multi-critical multi-field models: a CFT approach to the leading order

We present some general results for the multi-critical multi-field models in d>2 recently obtained using CFT and Schwinger-Dyson methods at perturbative level without assuming any symmetry. Results in the leading non trivial order are derived consistently for several conformal data in full agreement with functional perturbative RG methods. Mechanisms like emergent (possibly approximate) symmetries can be naturally investigated in this framework.Comment: 12 pages, 1 figure, Contribution to the Conference QFT2018, Quantum Fields From Fundamental Concepts to Phenomenological Questions, Mainz 26-28 September 201

The Denoised, Deconvolved, and Decomposed Fermi γ\gamma-ray sky - An application of the D3^3PO algorithm

We analyze the 6.5yr all-sky data from the Fermi LAT restricted to gamma-ray photons with energies between 0.6-307.2GeV. Raw count maps show a superposition of diffuse and point-like emission structures and are subject to shot noise and instrumental artifacts. Using the D3PO inference algorithm, we model the observed photon counts as the sum of a diffuse and a point-like photon flux, convolved with the instrumental beam and subject to Poissonian shot noise. D3PO performs a Bayesian inference in this setting without the use of spatial or spectral templates;i.e., it removes the shot noise, deconvolves the instrumental response, and yields estimates for the two flux components separately. The non-parametric reconstruction uncovers the morphology of the diffuse photon flux up to several hundred GeV. We present an all-sky spectral index map for the diffuse component. We show that the diffuse gamma-ray flux can be described phenomenologically by only two distinct components: a soft component, presumably dominated by hadronic processes, tracing the dense, cold interstellar medium and a hard component, presumably dominated by leptonic interactions, following the hot and dilute medium and outflows such as the Fermi bubbles. A comparison of the soft component with the Galactic dust emission indicates that the dust-to-soft-gamma ratio in the interstellar medium decreases with latitude. The spectrally hard component exists in a thick Galactic disk and tends to flow out of the Galaxy at some locations. Furthermore, we find the angular power spectrum of the diffuse flux to roughly follow a power law with an index of 2.47 on large scales, independent of energy. Our first catalog of source candidates includes 3106 candidates of which we associate 1381(1897) with known sources from the 2nd(3rd) Fermi catalog. We observe gamma-ray emission in the direction of a few galaxy clusters hosting radio halos.Comment: re-submission after referee report (A&A); 17 pages, many colorful figures, 4 tables; bug fixed, flux scale now consistent with Fermi, even lower residual level, pDF -> 1DF source catalog, tentative detection of a few clusters of galaxies, online material http://www.mpa-garching.mpg.de/ift/fermi

The Galaxy in circular polarization: all-sky radio prediction, detection strategy, and the charge of the leptonic cosmic rays

The diffuse Galactic synchrotron emission should exhibit a low level of diffuse circular polarization (CP) due to the circular motions of the emitting relativistic electrons. This probes the Galactic magnetic field in a similar way as the product of total Galactic synchrotron intensity times Faraday depth. We use this to construct an all sky prediction of the so far unexplored Galactic CP from existing measurements. This map can be used to search for this CP signal in low frequency radio data even prior to imaging. If detected as predicted, it would confirm the expectation that relativistic electrons, and not positrons, are responsible for the Galactic radio emission. Furthermore, the strength of real to predicted circular polarization would provide statistical information on magnetic structures along the line-of-sights.Comment: 11 pages, 5 figures, revise

Stochastic growth of quantum fluctuations during slow-roll inflation

We compute the growth of the mean square of quantum fluctuations of test fields with small effective mass during a slowly changing, nearly de Sitter stage which took place in different inflationary models. We consider a minimally coupled scalar with a small mass, a modulus with an effective mass $\propto H^2$ (with $H$ as the Hubble parameter) and a massless non-minimally coupled scalar in the test field approximation and compare the growth of their relative mean square with the one of gauge-invariant inflaton fluctuations. We find that in most of the single field inflationary models the mean square gauge invariant inflaton fluctuation grows {\em faster} than any test field with a non-negative effective mass. Hybrid inflationary models can be an exception: the mean square of a test field can dominate over the gauge invariant inflaton fluctuation one on suitably choosing parameters. We also compute the stochastic growth of quantum fluctuation of a second field, relaxing the assumption of its zero homogeneous value, in a generic inflationary model; as a main result, we obtain that the equation of motion of a gauge invariant variable associated, order by order, with a generic quantum scalar fluctuation during inflation can be obtained only if we use the number of e-folds as the time variable in the corresponding Langevin and Fokker-Planck equations for the stochastic approach. We employ this approach to derive some bounds in the case of a model with two massive fields.Comment: 9 pages, 4 figures. Added references, minor changes, matches the version to be published in Phys. Rev.